Investigation of Inductive Effects on the Transphosphorylation Reaction of Spin-Labeled Phosphoryl Imidazolides, Part II
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چکیده
Since we reported the synthesis of the first spinlabeled imidazolide of phosphorus, i.e., (1-oxyl2,2,6,6-tetramethyl-4-piperidyl) diimidazole-1,1'phosphinate (1), in 1973 [1], we have extensively studied the synthetic potential of imidazolide 1 and related compounds. Imidazolide 1 was utilized for the preparation of spin-labeled phosphates 2 and phosphoroamidates 3 [2, 3]. In most cases, imida-
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تاریخ انتشار 2012